You could try clear finger nail polish. It can be removed with acetone, and if you only put it around the edges of the chipped enamel, it will not change the appearance of the enamel itself. I think it would be easier to remove than white glue.
I don’t recall the particular brand. A good jeweler’s supply company will have cold enamels, get a starter kit and follow the directions to the letter. Rio Grande in Albuquerque, NM should be a great place to start.
"Cold enamels" search should reveal particulars.
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